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However, in the 1950s, increased demand for benzene, especially from the growing polymers industry, necessitated the production of benzene from petroleum. Ref. Structure and properties. on behalf of the United States of America. [30][37] Kekul used evidence that had accumulated in the intervening yearsnamely, that there always appeared to be only one isomer of any monoderivative of benzene, and that there always appeared to be exactly three isomers of every disubstituted derivativenow understood to correspond to the ortho, meta, and para patterns of arene substitutionto argue in support of his proposed structure. Zhur. Uchebn. Given that demand for para-xylene (p-xylene) substantially exceeds demand for other xylene isomers, a refinement of the TDP process called Selective TDP (STDP) may be used. Through calculating more than thirty parameters, Lonsdale demonstrated that the benzene ring could not be anything but a flat hexagon, and provided accurate distances for all carbon-carbon bonds in the molecule. Physical State (20 deg.C) Liquid. Zhur. Critically Evaluated Thermochemical Properties of Polycyclic Aromatic Hydrocarbons, If gloves are worn, PVA, butyl rubber and viton are suitable materials. The phase diagram of benzene is shown below the table. ; Hepler, L.G., Physik [3], 1881, 13, 447-464. [all data], Burlew, 1940 aggravated assault charge. I. [97] Benzene causes chromosomal aberrations in the peripheral blood leukocytes and bone marrow explaining the higher incidence of leukemia and multiple myeloma caused by chronic exposure. Data compiled as indicated in comments: Am. Cookies are only used in the browser to improve user experience. Department of Health and Human Services. ; Wilhelm, E.; Hamedi, M.H., J. (The specific heat of benzene is 1.740 J/g C). 1 C H vap (80. Contact China Manufactory Wuhan Kaimubuke Pharmaceutical Technology Co., Ltd for the product BERYLLIUM CHLORIDE. biphenyl (aka diphenyl) at higher temperature: If the raw material stream contains much non-aromatic components (paraffins or naphthenes), those are likely decomposed to lower hydrocarbons such as methane, which increases the consumption of hydrogen. [all data], Ogawa and Murakami, 1985 In 1865, the German chemist Friedrich August Kekul published a paper in French (for he was then teaching in Francophone Belgium) suggesting that the structure contained a ring of six carbon atoms with alternating single and double bonds. [all data], Williams and Daniels, 1925 Chem., 1978, 82, 1282-1290. Benzene has been shown to cause cancer in both sexes of multiple species of laboratory animals exposed via various routes. ; Picker, P., In 1988 it was reported that two-thirds of all chemicals on the American Chemical Society's lists contained at least one benzene ring. Replacing one CH with N gives the compound pyridine, C5H5N. J. 9.11 Ratio of Specific Heats of Vapor (Gas): 1.061 9.12 Latent Heat of Vaporization: 169 Btu/lb = 94.1 cal/g = 3.94 X 105 J/kg . J. Chem. J. Chem. DH - Eugene S. Domalski and Elizabeth D. Hearing, Go To: Top, Condensed phase thermochemistry data, Notes, Roux, Temprado, et al., 2008 [all data], Tschamler, 1948 The aromatic products of the reaction are then separated from the reaction mixture (or reformate) by extraction with any one of a number of solvents, including diethylene glycol or sulfolane, and benzene is then separated from the other aromatics by distillation. PubChem Substance ID. \Delta H of fusion for benzene is 9.87 kJ/mol; specific heat for liquid benzene is 1.63 J/g X degrees). Flammable, irritating vapor is produced. Molecular Weight 1 134.22 CAS 105-05-5 Other Names 1,4-DIETHYLBENZENE Benzene, p-diethyl- p-Diethylbenzene p-Ethylethylbenzene para-Diethylbenzene : Acentric Factor. Data, 1989, 34, 332-335. specific heat liquid = 1.740 J/g C A 27.00 g sample of liquid benzene is initially at 41.30 C. [16] An acidic material was derived from benzoin by sublimation, and named "flowers of benzoin", or benzoic acid. [85] This regulation is based on preventing benzene leukemogenesis. Excess thermodynamic functions of the systems: benzene + p-xylene and benzene + p-dioxan, Today, most benzene comes from the petrochemical industry, with only a small fraction being produced from coal. 125129. Tschamler, H., Benzene CCOHS. Calorimetry (Lect. Myeloperoxidase mutations result in loss of function and may result in decreased generation of toxic metabolites. Phys. He gave the compound the name benzin. It is a byproduct of the incomplete combustion of many materials. Thermodynam., 1993, 25(1), 41-50. Pure Benzene (C_6H_6) has a melting point of 5.5 degrees Celsius. In 1855, Hofmann used the word "aromatic" to designate this family relationship, after a characteristic property of many of its members. The specific heats of five organic liquids from their adiabatic temperature-pressure coefficients, Pol. [51], Trace amounts of benzene are found in petroleum and coal. ; Nikolaev, P.N., (The density of benzene is 0.80 g/mL, its specific heat capacity is 1.74 J/g K, and its heat of fusion is 127 J/g.) Determination of excess heat capacities of (benzene + tetrachloromethane and + cyclohexane) between 293.15 and 303.15 K by use of a Picker flow calorimeter, Bull. : Dynamic viscosity (Pas). It found that four contained benzene levels above World Health Organization limits. [83] The maximum allowable amount of benzene in workroom air during an 8-hour workday, 40-hour workweek is 1 ppm. The curve between the critical point and the triple point shows the benzene boiling point with changes in pressure. Staveley, L.A.K. Studies on the heat capacities at low temperature. [79][80], According to the Agency for Toxic Substances and Disease Registry (ATSDR) (2007), benzene is both a synthetically-made and naturally occurring chemical from processes that include: volcanic eruptions, wild fires, synthesis of chemicals such as phenol, production of synthetic fibers, and fabrication of rubbers, lubricants, pesticides, medications, and dyes. Ser. Are fluid 5. Thermodynamic properties of benzene, Chem., 1965, 96, 669-678. Mean specific heat in homologous series of binary and ternary positive azeotropes, . Mitt. Q = joules = x 10^ joules. BENZENE BNZ CAUTIONARY RESPONSE INFORMATION Common Synonyms Watery liquid Colorless Gasoline-like odor Floats on water. Measurement of thermal properties of liquids with an AC heated-wire technique, Calorimetric determinations of thermal properties of methyl alcohol, ethyl alcohol, and benzene, Soc., 1940, 62, 696-700. Excess volumes and excess heat capacities of 2,3-dimethylbutane + butane and + toluene, ; Shipova, V.A., Benzene - Density and Specific Weight vs. The specific heat of a substance is the amount of energy that must be transferred to or from 1 g of that substance to change its temperature by 1. This is often called "on-purpose" methodology to produce benzene, compared to conventional BTX (benzene-toluene-xylene) extraction processes. In particular, acute myeloid leukemia or acute nonlymphocytic leukemia (AML & ANLL) is caused by benzene. Fortier, J.-L.; Benson, G.C. Kalali, H.; Kohler, F.; Svejda, P., ; T = 280 to 353 K. Data also given by equation. Complete decarboxylation of mellitic acid gives benzene. Ethyl alcohol likely exhibits more hydrogen bonding than water. Benzene should NOT be used at all unless no safer alternatives are available. Chem. Several enzymes are involved. [all data], Tanaka, 1985 As a consequence, gasoline often contained several percent benzene before the 1950s, when tetraethyl lead replaced it as the most widely used antiknock additive. ; Bhatagadde, L.G., He said that he had discovered the ring shape of the benzene molecule after having a reverie or day-dream of a snake biting its own tail (this is a common symbol in many ancient cultures known as the Ouroboros or endless knot). [98] Benzene metabolism involves enzymes coded for by polymorphic genes. Specific heat of benzenoid hydrocarbons, Because it contains only carbon and hydrogen atoms, benzene is classed as a hydrocarbon.[15]. [all data], Prosen, Johnson, et al., 1946 ), pp. Archibald Scott Couper in 1858 and Johann Josef Loschmidt in 1861[36] suggested possible structures that contained multiple double bonds or multiple rings, but too little evidence was then available to help chemists decide on any particular structure. Am. Follow us on Twitter Question, remark ? [all data], Oliver, Eaton, et al., 1948 CAS RN. [22] Four years later, Mansfield began the first industrial-scale production of benzene, based on the coal-tar method. Eliminate heat and ignition sources such as sparks, open flames, hot surfaces and static A typical reaction yield exceeds 95%. [68] European petrol specifications now contain the same 1% limit on benzene content. Am. Have definite shape (resist deformation) 2. [all data], Kurbatov, 1947 Maleic anhydride is widely used in resins, coating, pharmaceuticals, surfactants, agricultural products, and plastics. Curiously, a similar, humorous depiction of benzene had appeared in 1886 in a pamphlet entitled Berichte der Durstigen Chemischen Gesellschaft (Journal of the Thirsty Chemical Society), a parody of the Berichte der Deutschen Chemischen Gesellschaft, only the parody had monkeys seizing each other in a circle, rather than snakes as in Kekul's anecdote. Storage class Storage class (TRGS 510): 3: Flammable liquids 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated SECTION 8: Exposure controls/personal protection Equation 1. Uber binare flussige Mischungen I. Mischungswarment, Volumseffekte und Zustandsdiagramme von chlorex mit benzol und n-alkylbenzolen, [107][108], This article is about the chemical compound. Compound Name: Benzene; Formula: C6H6; at Temperature: ; Badalov, Yu.A., Die aromatischen Verbindungen. ; Roux-Desgranges, G.; Kooner, Z.S. Heats of combustion of benzene, toluene, ethyl-benzene, o-xylene, m-xylene, p-xylene, n-propylbenzene, and styrene, Six-membered aromatic rings with one carbon replaced by another element: This page was last edited on 15 February 2023, at 05:01. Benzeneis present in crude oils and is a product of oil-refining processes. ; Ganiev, Yu.A., [86] These legal limits were based on studies demonstrating compelling evidence of health risk to workers exposed to benzene. The proportionality constant c is sometimes referred to as the specific heat capacity or (incorrectly) the heat capacity. *** Very flammable. Please read AddThis Privacy for more information. Mixtures containing N,N-dimethylformamide, Specific Heat Search. The new understanding of benzene, and hence of all aromatic compounds, proved to be so important for both pure and applied chemistry that in 1890 the German Chemical Society organized an elaborate appreciation in Kekul's honor, celebrating the twenty-fifth anniversary of his first benzene paper. The specific heats of certain organic liquids at elevated temperatures, Some of our calculators and applications let you save application data to your local computer. X-ray diffraction shows that all six carbon-carbon bonds in benzene are of the same length, at 140 picometres (pm). With the global phaseout of leaded gasoline, benzene has made a comeback as a gasoline additive in some nations. Benzene causes cancer in animals including humans. Table 7.2. Diffuse through otherliquids 6. 2. to the boiling point, Ramadevi Punyamurthy et al. Excess properties of the mixture bis(2-dichlorethyl)ether (chlorex) + 2,2,4-trimethylpentane (isooctane), However, NIST makes no warranties to that effect, and NIST . Tanaka, R., Contact us at contact@myengineeringtools.com 1. In another human study, 30% of absorbed dermally applied benzene, which is primarily metabolized in the liver, was excreted as phenol in the urine. The major sources of benzene exposure are tobacco smoke, automobile service stations, exhaust from motor vehicles, and industrial emissions; however, ingestion and dermal absorption of benzene can also occur through contact with contaminated water. The hydrocarbon derived from benzoic acid thus acquired the name benzin, benzol, or benzene. and final temperature T f = C = K = F, Q = calories = kcal = x 10^ calories. [all data], Lainez, Rodrigo, et al., 1989 Similar problems were reported by the FDA in the United States.[104]. Short Commun. ; Roux-Desgranges, G.; Berkane, M.; Jimenez, E.; Wilhelm, E., Bull. Kurbatov, V.Ya., For a given species, see the thermodynamic values below. Benzene is an organic chemical compound with the . When plastic water pipes are subject to high heat, the water may be contaminated with benzene. Excess molar isobaric heat capacities and isentropic compressibilities of (cis- or trans-decalin + benzene or toluene or iso-octane or n-heptane) at 298.15 K, Data, 1986, 31, 238-240. Benzene - Density and Specific Weight vs. [106], The Nazis used benzene administered via injection as one of their many methods for killing. *** Very flammable. reddens or appears damaged, call for medical aid. J. Thermophysics, 1982, 3, 1-15. C11H16 = 148.25. [47][48] It was the German chemist Carl Grbe who, in 1869, first used the prefixes ortho-, meta-, para- to denote specific relative locations of the substituents on a di-substituted aromatic ring (viz, naphthalene). [81], Exposure to benzene may lead progressively to aplastic anemia, leukaemia, and multiple myeloma. Substantial quantities of epidemiologic, clinical, and laboratory data link benzene to aplastic anemia, acute leukemia, bone marrow abnormalities and cardiovascular disease. Therefore, between the carbon atoms of benzene there were no fixed (i.e., constant) and distinct single or double bonds; instead, the bonds between the carbon atoms were identical. A mixture of 54.5 mol% benzene in chlorobenzene at its bubble point is fed continuously to the bottom plate of a column containing two equilibrium plates, with a partial reboiler and a total condenser. Chem. Pyrolysis gasoline can be blended with other hydrocarbons as a gasoline additive, or routed through an extraction process to recover BTX aromatics (benzene, toluene and xylenes). [all data], Wilhelm, Grolier, et al., 1977 Using a precise scanning-microcalorimetric technique, the heat-capacity difference between water and an aqueous solution of benzene or of toluene has been measured for a broad temperature range (from 278 to 413 K) under excess pressure, and the partial specific heat capacity of these solutes has been determined. The pure material, and any solutions containing it, constitute a fire risk. 8600 Rockville Pike, Bethesda, MD, 20894 USA. The solvent-properties of the two are similar, but toluene is less toxic and has a wider liquid range. von Reis, M.A., [all data], Willams and Daniels, 1924 Benzene is a natural constituent of petroleum and is one of the elementary petrochemicals. Here Kekul spoke of the creation of the theory. The most important variations contain nitrogen. [all data], Gorbunova, Grigoriev, et al., 1982 J. This amount is about 10 times the average daily intake of benzene by nonsmokers. The idea is used in fireworks to produce the colour. rend., 1933, 197, 519-520. Am. You can target the Engineering ToolBox by using AdWords Managed Placements. Specific Heat of Benzene, Specific Heat of C6H6. Thus, a double bond would exist with one neighbor during the first interval and with the other neighbor during the next interval. ; T = 93 to 300 K. Value is unsmoothed experimental datum. The Cl , Br and CN nucleophiles can easily be introduced in the benzene ring of benzene diazonium salt in the presence of Cu(I) ion. National Institute of Standards and [96], The paradigm of toxicological assessment of benzene is shifting towards the domain of molecular toxicology as it allows understanding of fundamental biological mechanisms in a better way. Anal. Heat capacities at constant volume, free volumes, and rotational freedom in some liquids, Benzene is hepatically metabolized and excreted in the urine. The heat capacity, heat of fusion and entropy of benzene, Benzene Gas - Specific Heat vs. (This estimate assumes no threshold for benzene's carcinogenic effects.) In the bone marrow, MPO converts these polyphenols to benzoquinones. Energy released when benzene converts from 100oC to 80oC (in this range it is gas as temperature>Boiling . The most widely practiced example of this reaction is the ethylation of benzene. Grolier, J.-P.E. ; Everett, D.H., The triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium. Ferguson, A.; Miller, J.T., ; Gilmont, R.; Rossini, F.D., [citation needed], Several tests can determine exposure to benzene. Ogawa, H.; Murakami, S., Excess volumes and excess heaat capacitiies of some mixtures with trans,trans,cis-1,5,9-cyclododecatriene at 298.15K, You will need these items: T-shirt Ironing board Iron Wax paper Towel or rag Step 1: Ethylbenzene Formula: C 8 H 10 Molecular weight: 106.1650 IUPAC Standard InChI: InChI=1S/C8H10/c1-2-8-6-4-3-5-7-8/h3-7H,2H2,1H3 IUPAC Standard InChIKey: YNQLUTRBYVCPMQ-UHFFFAOYSA-N CAS Registry Number: 100-41-4 Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file These aberrations can be monitored using fluorescent in situ hybridization (FISH) with DNA probes to assess the effects of benzene along with the hematological tests as markers of hematotoxicity. heat [1] 3. Acad. Some thermodynamice properties of the systems benzene + ethylene dichloride, benzene + carbon tetrachloride, acetone + chloroform, and acetone + carbon disulphide, Chem. The short term exposure limit for airborne benzene is 5 ppm for 15 minutes. Ann. [90] The NIOSH short-term exposure limit (STEL 15 min) is 1 ppm. Google use cookies for serving our ads and handling visitor statistics. Gorbunova, N.I. ; Gruber, K.; Pereira, J.F. Expert Answer. Am. We don't collect information from our users. Benzene is sufficiently nucleophilic that it undergoes substitution by acylium ions and alkyl carbocations to give substituted derivatives. In the absence of the catalyst, benzene is impervious to hydrogen. This page provides supplementary chemical data on benzene. See also the following documents for changes in benzene properties with changes in pressure and temperature: See also more about atmospheric pressure, and STP - Standard Temperature and Pressure & NTP - Normal Temperature and Pressure, as well as Thermophysical properties of: Acetone, Acetylene, Air, Ammonia, Argon, Butane, Carbon dioxide, Carbon monoxide, Ethane, Ethanol, Ethylene, Helium, Hydrogen, Hydrogen sulfide, Methane, Methanol, Nitrogen, Oxygen, Pentane, Propane, Toluene, Water and Heavy water, D2O. Reddy, K.S., Contact. [all data], Kolosovskii and Udovenko, 1934 ; Nagano, Y., Tohoku Imp. (TLV) for benzene to 0.02 ppm and reduce the 15 . Instead, retain in a safe place in the laboratory (well away from any source of ignition). The specific heat capacity of liquid water is 4.18 J/g-K. How many joules of heat are needed to raise the temperature of 5.00 g of water from 25.1C to 65.3C? The current NIOSH definition for an IDLH condition, as given in the NIOSH Respirator Selection Logic, is one that poses a threat of exposure to airborne contaminants when that exposure is likely to cause death or immediate or delayed permanent adverse health effects or prevent escape from such an environment. [101] After smoking 32 cigarettes per day, the smoker would take in about 1.8 milligrams (mg) of benzene. Phenol and halobenzenes can be reduced with metals. Vyssh. Vys. Hyder Khan, V.; Subrahmanyam, S.V., Benzene depletion in a laminar premixed flat stoichiometric low-pressure methane/air/benzene (1.5%) flame was investigated using a recently developed kinetic model that has been tested for low-pressure combustion of acetylene, ethylene, and benzene.Experimental flame structures of two stoichiometric methane/air flames (v =34.2 cm s 1, 5.33 kPa) with and without the addition of 1.5% of . ; Wilhelm, E.; Grolier, J.-P.E., Nitrobenzene is the precursor to aniline. In catalytic reforming, a mixture of hydrocarbons with boiling points between 60 and 200C is blended with hydrogen gas and then exposed to a bifunctional platinum chloride or rhenium chloride catalyst at 500525C and pressures ranging from 850 atm. [all data], Wilhelm, Faradjzadeh, et al., 1982 ; Jost, W., Conf. Sulfonated benzene derivatives are useful detergents. [all data], von Reis, 1881 All rights reserved. Ber. Specific heat of sulphuric acid= 1.40 . Chem., 1971, 24, 1817-1822. Specific target organ toxicity - single exposure (narcotic effects) - Category 3 - Narcotic effect. Replacement of a second CH bond with N gives, depending on the location of the second N, pyridazine, pyrimidine, or pyrazine. Ser. Technology, Office of Data [103], Under specific conditions and in the presence of other chemicals benzoic acid (a preservative) and ascorbic acid (Vitamin C) may interact to produce benzene. Many important chemical compounds are derived from benzene by replacing one or more of its hydrogen atoms with another functional group. Studies have shown that genotype at these loci may influence susceptibility to the toxic effects of benzene exposure. Chem., 1948, 79, 162-177. Trans. [all data], Shiohama, Ogawa, et al., 1988 Pure benzene, for example, oxidizes in the body to produce an epoxide, benzene oxide, which is not excreted readily and can interact with DNA to produce harmful mutations. Monatsh. Phys. Keep locked up or in an area accessible only to qualified or authorized persons. K) ..g (K) | 1 mol All you need to do is convert the grams to moles. Kalorimetrische Messungen an Mischungen von Nichtelektrolyten, 1. Centric affinities (i.e., bonds) acted within a designated cycle of carbon atoms. Benzene itself can be measured in breath, blood or urine, but such testing is usually limited to the first 24 hours post-exposure due to the relatively rapid removal of the chemical by exhalation or biotransformation. The specific heat capacity is the heat or energy required to change one unit mass of a substance of a constant volume by 1 C. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Khim., 1941, 11, 471-482. Czech. In his 1890 paper, Armstrong represented benzene nuclei within polycyclic benzenoids by placing inside the benzene nuclei a letter "C", an abbreviation of the word "centric". In this hydrogen-intensive process, toluene is mixed with hydrogen, then passed over a chromium, molybdenum, or platinum oxide catalyst at 500650C and 2060 atm pressure. J. Benzene causes central nervous system damage acutely and bone marrow damage chronically and is carcinogenic. Acta, 1967, 37, 200-208. J. Chem. Tanaka, R., The reaction involves the acylation of benzene (or many other aromatic rings) with an acyl chloride using a strong Lewis acid catalyst such as aluminium chloride or Iron(III) chloride. Monatsh. There are sufficient high-quality literature values to make a good evaluation with a high degree of confidence. Aoyama, S.; Kanda, E., However, if heated it becomes a gas, and when cooled it becomes a solid. ; Hart, K.R., Benzene: Patient information sheet, "Drinking Water Contaminants | Organic Chemicals | Benzene", "Benzene Toxicity: Standards and Regulations", "Documentation for Immediately Dangerous to Life or Health Concentrations (IDLH): Introduction", "Blood concentrations of volatile organic compounds in a nonoccupationally exposed US population and in groups with suspected exposure", "100 tonnes of pollutants spilled into Chinese river", "Drinking water contamination from the thermal degradation of plastics: Implications for wildfire and structure fire response", "A Former Nazi Labor Camp in Austria, Now Billed as a Tourist Site", Dept. [100] About 50% of the entire nationwide (United States) exposure to benzene results from smoking tobacco or from exposure to tobacco smoke. [all data], Ahlberg, Blanchard, et al., 1937 The next year he published a much longer paper in German on the same subject. In industrybenzeneis used as a solvent, as a chemical intermediate, and is used in the synthesis of numerous chemicals. To examine the effects of suppression of NOS activity on hematopoietic stem cells, we treated animals with NOS inhibitors or with control saline solution for 6 or 12 days and analyzed the changes in long-term engraftment of cells from these animals using a competitive repopulation assay: we mixed BM cells from the treated animals expressing the Ly-5.1 (CD45.1) alloantigen with a 4-fold excess . [all data], Atalla, El-Sharkawy, et al., 1981 Wear safety glasses and use protective gloves. Outdoor air may contain low levels of benzene from automobile service stations, wood smoke, tobacco smoke, the transfer of gasoline, exhaust from motor vehicles, and industrial emissions. Manufacture of some of these benzene-containing formulations ceased in about 1950, although Liquid Wrench continued to contain significant amounts of benzene until the late 1970s. Nauk, 1962, SSSR 142, 1335-1338. France, 1929, 45, 36-49. 1. The United States Environmental Protection Agency has set a maximum contaminant level for benzene in drinking water at 0.0005mg/L (5 ppb), as promulgated via the U.S. National Primary Drinking Water Regulations. Burlew, J.S., Aust. American Conference of Governmental Industrial Hygienists (ACGIH) adopted Threshold Limit Values (TLVs) for benzene at 0.5 ppm TWA and 2.5 ppm STEL. Benzene, C6H6, is a clear colorless to light-yellow liquid, flammable with a petroleum-like, aromatic odor. This process was later discontinued. Engineering ToolBox - Resources, Tools and Basic Information for Engineering and Design of Technical Applications! Univ. Cp,gas : Ideal gas heat capacity (J/molK). Grolier, J.-P.E. Eng. Benzene has 6 hydrogen atoms, fewer than the corresponding parent alkane, hexane, which has 14. [all data], Huffman, Parks, et al., 1930 The reaction of the diazonium compound derived from aniline with hypophosphorus acid gives benzene. Add standard and customized parametric components - like flange beams, lumbers, piping, stairs and more - to your Sketchup model with the Engineering ToolBox - SketchUp Extension - enabled for use with the amazing, fun and free SketchUp Make and SketchUp Pro .Add the Engineering ToolBox extension to your SketchUp from the SketchUp Pro Sketchup Extension Warehouse! Benzene (CAS 71-43-2) 1 Carcinogenic to humans. When gasoline burns, the benzene reacts with oxygen. (VIII. J. Chem. Devon is applying 100N of . Reaxys Registry Number. Izv. Please read Google Privacy & Terms for more information about how you can control adserving and the information collected. Benzene: 0.085: 2.7: 4.0: 1460: Hexane: . [all data], Andrews, Lynn, et al., 1926 Zhur. Sci. MSDS for benzene is available at AMOCO. Neft Gaz. Sci., 1969, 38, 510-511. Flow microcalorimeter for heat capacities of solutions, Note: (s) notation indicates equilibrium temperature of vapor over solid, otherwise value is equilibrium temperature of vapor over liquid. Measurement of the heat capacity of a small volume of liquid by the piezo-thermometric method. Class XII. J. Naziev, Ya.M. [78] IARC rated benzene as "known to be carcinogenic to humans" (Group 1). Isotopic effect in the specific heat of some deutero compounds, Shiohama, Y.; Ogawa, H.; Murakami, S.; Fujihara, I., Excess volumes and excess heat capacities of tetrachloroethene + cyclohexane, + methylcyclohexane, + benzene, and + toluene at 298.15 K, In the United States, concern over its negative health effects and the possibility of benzene entering the groundwater has led to stringent regulation of gasoline's benzene content, with limits typically around 1%. Chemical Properties of Ethylbenzene (CAS 100-41-4) InChI InChI=1S/C8H10/c1-2-8-6-4-3-5-7-8/h3-7H,2H2,1H3 InChI Key YNQLUTRBYVCPMQ-UHFFFAOYSA-N Formula C8H10 SMILES CCc1ccccc1 Molecular Weight 1 106.17 CAS 100-41-4 Other Names .alpha.-methyltoluene Aethylbenzol Benzene, ethyl- EB Ethylbenzeen Ethylbenzol Etilbenzene Etylobenzen NCI-C56393 NSC 406903 [all data], Deshpande and Bhatagadde, 1971 Soc. Most people in developed countries have measureable baseline levels of benzene and other aromatic petroleum hydrocarbons in their blood. Bull. Heats of combustion and formation at 25C of the alkylbenzenes through C10H14, and of the higher normal monoalkylbenzenes,

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